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Plasma Treatment of PDMS leads to Improved Adhesion / Bonding

Plasma Treatment of PDMS for improved adhesion/bonding performance of microfluidic devices – new application note available now.

What is PDMS?

Polydimethylsiloxane (PDMS) – is a member of a group of polymeric organosilicon compounds that are widely known as silicones.

Hexagons showing images - Plasma Treatment of PDMS

It is the most widely used of these compounds and is featured in applications ranging from medicines and cosmetics to silly putty. In this application, we concentrate on the use of PDMS in microfluidic device fabrication.

PDMS-Chemical-structure - Plasma Treatment of PDMS

Fig 1. Molecular structure of PDMS.

Why PDMS?

PDMS has a number of properties which make it favourable for use in creating microfluidic devices.

  • Biocompatible
  • Low cost
  • Few nm resolution moulding
  • Low autofluorescence
  • Transparent (240nm – 1100nm range)

Despite these advantages, PDMS has one key limitation, it’s poor adhesion to glass. When used in the microfluidic application this can lead to premature device failure. Henniker’s systems are routinely used for plasma surface treatment of PDMS in microfluidic laboratories throughout the world, here we show you how to achieve optimal device bonding results using our equipment.

Our Solution

The Henniker HPT-200 system is developed and optimised to produce consistent plasma treatment performance for reliable & repeatable bonding of PDMS. Both the glass and PDMS substrates are treated with air plasmas, at low pressure, with all settings under microprocessor control.

Henniker's plasma treatment system - HPT-100 HPT-200

On both substrates, the treatment is effective at removing hydrocarbon groups (CxHy) leaving behind silanol groups on the PDMS and OH groups on the glass substrate respectively. This allows strong Si – O – Si covalent bonds to form between the two materials via the process as shown in Fig 2.

Plasma Treatment of PDMS - Henniker-Plasma-Treatment-PDMS-bonding-mechanism

Plasma Treatment of PDMS - Henniker Plasma Treatment of PDMS & Glass for Improved Adhesion

Fig 2. Schematic diagram of the plasma treatment process to improve surface adhesion

Results

Contact Angle Measurements

Contact angle measurements indicate whether a surface is hydrophobic (over 90°) or hydrophilic (under 90°) by the angle a water drop makes with the surface. Here we can see that increasing the time or power of an air plasma treatment on PDMS leads to the surface becoming more hydrophilic.Plasma Treatment of PDMS-Graphs-showing-adhesion-improvement-using-contact-angle

Fig 3. Contact angle variations with increasing treatment time at 25% power (left) and increasing power with 10secs exposures (right). Both show a switch between hydrophobic to hydrophilic behaviour. Insets show example droplets.

This switch to more hydrophilic behaviour shows that the proposed treatment has been a success and that the – OH termination associated with silanol groups is now exposed, leading to improved bonding of the PDMS to the glass substrates.

X-ray photoelectron spectroscopy (XPS)

XPS is a widely used technique to analyse the functional groups present on the surface of a substrate. Here we use XPS to show how C-O groups are absent prior to plasma treatment (in this case with oxygen plasma) and present after the treatment. Thus indicating a successful surface modification.

Plasma Treatment of PDMS - XPS Results PDMS Untreated

Plasma Treatment of PDMS - XPS Results

Fig 4. XPS results from untreated (Top) and oxygen treated (Bottom) samples highlighting the presence of C-O groups after treatment.

Conclusions

Bonding of PDMS to glass is a key issue in the use of the material in fabricating microfluidic devices, however when using a Henniker model HPT-200 benchtop plasma system to treat PDMS substrates alongside glass substrates, this problem has been addressed. Plasma treatment has been shown to improve the wettability of both surfaces. Leading to increased bonding between the 2 substrates which is highlighted in Fig 6.

The system can also be optimised to bond PDMS to thermoplastic materials.

Plasma Treatment of PDMS - Microfluidics-being-plasma-treated-in-an-oxygen-plasma

Fig 5.  PDMS microfluidic channels undergoing plasma treatment.

PDMS on the glass substrate after plasma treatment

Fig 6. Bonded PDMS and glass following a plasma treatment in a Henniker HPT-200 machine.

Acknowledgements
We gratefully acknowledge the input and discussion with Dr Alex Iles of the Pamme Group at Hull University, UK.

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